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SOLVED: Procedure for Synthesis of an Oxime Compound(Cyclohexanone Oxime)1. To 2 grams of hydroxylamine hydrochloride dissolved in 4 mL of water, add 4 mL of 30% NaOH solution. Cool in ice water and add 3.5 mL of cyclohexanone, slowly and with vigorous shaking.2. Reflux with stirring for 15-30 minutes. While still hot, transfer the warm solution to an Erlenmeyer flask or beaker. Let cool to room temperature, then place in an ice-water bath until crystallization is complete. Then, collect the oxi
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SOLVED: Draw the structural formula of diisopentyl ketone.Draw the structural formula of 2,4-pentanedione.Draw the structure of the oxime of cyclopropanone.Which compound is the tertiary (3°) amide?None of the above.CH3NH2H3CCH2CH3The reaction of 1-pentanol with Jones reagent (CrO3/H2SO4) gives aldehyde, ketone, and carboxylic acid.
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SOLVED:A clever new method of peptide synthesis involves formation of an amide bond by reaction of an α-keto acid with an N -alkylhydroxylamine: CAN'T COPY THE FIGURE The reaction is thought to occur by nucleophilic addition of the N-alkylhydroxylamine to the keto acid as if forming an oxime (Section 19.8 ), followed by decarboxylation and elimination of water. Show the mechanism.
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