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2:55
Synthesis of 1,3-substituted Pyrazole from Diarylhydrazone and Vicinal Diol - Labmonk
1,3-substituted pyrazole is prepared by cyclization of diarylhydrazone and vicinal diol in presence of fecl3 & tert-butylhydroperoxide
labmonk.com
Mar 24, 2019
Diol Synthesis
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SOLVED:A vicinal diol has OH groups on adjacent carbons. The dehydration of a vicinal diol is accompanied by a rearrangement called the pinacol rearrangement. Propose a mechanism for this reaction.
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A vicinal diol has two alcoholic groups present :
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Write reactions for the action of the following reagents on p-chlorobenzaldehyde. Ethane-1,2-diol in presence of dry HCl. - Chemistry | Shaalaa.com
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SOLVED: The diol shown undergoes reactions with reducing and oxidizing agents to yield two different major organic products for each of the reactions: A and B. Draw the reactions shown:(A) Reaction with MnO in propione(B) Reduction with KMnO4 and heat, followed by an acidic aqueous workup
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