Chimoio is the capital of Manica Province in Mozambique. It is the fifth-largest city in Mozambique. Chimoio's name under Portuguese admiā¦Chimoio is the capital of Manica Province in Mozambique. It is the fifth-largest city in Mozambique. Chimoio's name under Portuguese administration was Vila Pery. Vila Pery developed under Portuguese rule as an important agricultural and textiles centre.